3 / 2021-09-29 20:25:25

An application of safety assessment for radioactive waste repository: non-equilibrium transport of Tritium, Selenium and Cesium in crushed granite with different path lengths

non-equilibrium; selenium; cesium; retardation factor; dispersion coefficient; breakthrough curves; STANMOD simulation

Abstract: Advection-dispersion experiments (ADE) were effectively designed for inadequate transport models through a calibration/validation process. HTO, selenium (Se), and cesium (Cs) transport in crushed granite were studied using a highly reliable, dynamic column device in order to obtain the retardation factors (R) and the dispersion coefficients (D) by fitting experimental breakthrough curves (BTCs) for various path lengths. In order to conduct a safety assessment (SA) of a deep geological repository for high-level radioactive waste, radionuclide transport  in rock systems is necessary to clarify and establish a suitable model. A dynamic column with a radiotracer (HTO, Se(IV), and Cs) was applied to 2, 4 and 8 cm path lengths using a STANMOD simulation; The results showed similar results between the BTCs of Se and Cs by fitting a non-equilibrium sorption model due to the retardation effect. In fact, there was a relatively obvious sorption of Se and Cs in the BTCs obtained by fitting a retardation factor (R) value higher than 1. In addition, two-region (physical) and two-site (chemical) non-equilibrium model with either a lowest sum of squared residuals (SSQ) or the root mean square error (RMSE) were applied to determine the Se and Cs sorption mechanism on granite.